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Bechamp reduction : ウィキペディア英語版
Bechamp reduction
The Bechamp reduction is used to reduce aromatic nitro compounds to their corresponding anilines, using iron and hydrochloric acid.〔Org React 2, 428 (1944).〕
This reaction was originally used to produce large amounts of aniline for industry, but catalytic hydrogenation is the preferred method. The Bechamp reaction is of interest as a route to iron oxide pigments.〔Thomas Kahl, Kai-Wilfrid Schröder, F. R. Lawrence, W. J. Marshall, Hartmut Höke, Rudolf Jäckh "Aniline" in Ullmann's Encyclopedia of Industrial Chemistry 2007; John Wiley & Sons: New York.〕
The reaction was first used by Antoine Béchamp to reduce nitronaphthalene and nitrobenzene in 1854.
==Reaction scope==
(詳細はAliphatic nitro compounds are more difficult to reduce, often remaining as the hydroxylamine. Tertiary aliphatic nitro compounds, however, are converted in good yield to the amine compound using the Bechamp reduction.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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